Integrated drying and gasification process for simultaneously producing synthetic gas and high rank coal

ABSTRACT

The present invention relates to a gasification process for efficiently co-producing synthesis gas and high-grade coal from water-containing coal, and to an integrated drying and gasification system for realizing the same.

BACKGROUND OF THE INVENTION

1. Technical Field

This application claims the benefit of priority No. KR2012-0149326 filedon Dec. 20, 2012.

The present invention relates to a gasification process for co-producingsynthesis gas and high-grade (high-quality) coal from water-containingcoal. More particularly, the present invention relates to a gasificationprocess in which a dryer for drying water-containing coal (feedstock)using the heat of synthesis gas is disposed in front of a gasifier,whereby dried coal can be easily transferred to the gasifier by anon-mechanical valve-type transfer means, and synthesis gas andhigh-quality coal containing a very small amount of water can beco-produced, and to an integrated drying and gasification system forrealizing the same.

2. Description of the Related Art

Generally, a gasification process is a series of processes forconverting a carbonaceous feedstock such as coal, biomass or the likeinto synthesis gas containing hydrogen and carbon monoxide as majorcomponents using a gasification reaction under the supply of a gasifyingagent (for example, oxygen, steam, carbon dioxide or a mixture thereof).In this case, the term “synthesis gas” generally means a gas mixtureincluding CO and H₂. Examples of typical reaction mechanisms of such agasification process are represented by the following Reaction Formulae1 to 3.

C+½O₂→CO(partial oxidation)  [Reaction Formula 1]

C+H₂O→CO+H₂(steam reforming)  [Reaction Formula 2]

C+CO₂→2CO(carbon dioxide reforming)  [Reaction Formula 3]

Recently, a gasification process has been diversified into various kindsof technologies for producing various compounds, and application fieldsthereof have spread in order to produce various products includingelectric power. Specifically, it is known that a gasification processcan be applied to power generation, ammonia preparation, oil refiningand the like using hydrogen and carbon monoxide included in synthesisgas which is a main product of a gasification process; that it can beused to produce diesel oil, jet oil, lubricant base oil, naphtha and thelike using synthesis gas as a feedstock of Fischer-Tropsch reactionrepresented by the following Reaction Formula 4; and that it can be usedto produce high value-added chemical materials such as acetic acid,olefin, dimethyl ether, aldehyde, fuel, additives and the like usingmethanol prepared from synthesis gas as represented by the followingReaction Formula 5. In relation to this gasification process, in thecase of Fischer-Tropsch process and methanol synthesis process, it ispreferred that the ratio of carbon monoxide to hydrogen be about 1:2.

nCO+2nH₂→C_(n)H_(2n) +nH₂O  [Reaction Formula 4]

CO+2H₂→CH₃OH  [Reaction Formula 5]

However, in the case of synthesis gas obtained by the steam reformingreaction represented by Reaction Formula 2 above and the carbon dioxidereforming reaction represented by Reaction Formula 3 above, the ratio ofcarbon monoxide to hydrogen does not reach 1:2. Therefore, generally,the ratio of carbon monoxide to hydrogen may be adjusted to about 1:2 byperforming the water-gas-shift reaction of a reaction product obtainedafter a steam reforming reaction, a partial oxidation reaction and/or acarbon monoxide reforming reaction or by additionally supplying hydrogento the reaction product.

CO+H₂O→CO₂+H₂  [Reaction Formula 6]

Meanwhile, since coal, which a typical feedstock in a gasificationprocess, is distributed in large quantities over a wide area throughoutthe world, it is attracting considerable attention again as a fuelsource that can replace petroleum that is commonly used at the presenttime. Further, since biomass, which has recently attracted attention,can also be converted into a basic fraction of various kinds of fuelsand platform compounds by various treatment processes, there is a knowntechnology of applying biomass as a feedstock in a gasificationreaction.

However, the above-mentioned feedstock in a gasification processcontains a large amount of water. For example, coals are classified intohigh-grade coal and low-grade coal depending on the properties thereof,such as heating value, water content, impurities, etc. Here, it is knownthat the amount of low-grade coal (brown coal, etc.) reserves occupiesabout 45% of the total amount of coal reserves throughout the world.Particularly, when the content of water in coal is high, the coalbecomes poor in terms of storability, treatability, freight and thelike, so a large amount of energy is consumed to remove water from thecoal prior to a gasification reaction.

In relation to this, U.S. Pat. Nos. 5,695,532 and 5,685,138 disclosetechnologies for using the heat of synthesis gas to dry awater-containing carbonaceous feedstock by disposing a dryer in front ofa gasification reactor and recycling the high-temperature synthesis gasgenerated from the gasification reactor into the dryer.

However, in order to supply the dried feedstock into an operatinggasifier at high pressure, it is required that the supply pressure ofthe dried feedstock is higher than the operating pressure of thegasifier. Conventionally, in order to supply the feedstock (dry coal)dried by synthesis gas into a gasifier, a pressurization feedstocksupply system including a buffer bin and a pressure lock hopper has beenused. However, this pressurization feedstock supply system isproblematic in that it is expensive and complicated and its operationlogic must be elaborately adjusted. Particularly, when dried coal iscarried to the gasifier using the pressure lock hopper, first, driedcoal is transferred to the buffer bin, and is then supplied to thegasifier together with carrier gas with the dried coal being pressurizedby the pressure lock hopper. In this case, the operation of a valve, thepressurization and depressurization of the pressure lock hopper, and thelike must be accurately adjusted.

Further, synthesis gas is discharged from a gasifier at high temperature(1000 to 1500□), whereas synthesis gas having relatively low temperature(about 500□) may also be used in order to dry water-containing coal. Forthis reason, in conventional technologies, in order to supply thermalenergy suitable for drying a water-containing feedstock introduced intoa dryer, a heat exchanger is disposed behind a gasifier to decrease thetemperature of the feedstock to the temperature of synthesis gas, andthen the feedstock is recycled or is cooled to a temperature suitablefor subsequent processes (for example, water-gas-shift reaction).

In this case, solid fuel dried by dryer, particularly, dried coal hashigher quality than water-containing coal. Therefore, if suchhigh-quality solid fuel (that is, dried coal) can be produced such thatit is used as a feedstock for a gasification reaction as well as isapplied to other uses, the added value in the total process will beincreased. However, in order to produce a feedstock for a gasificationreaction and high-quality solid fuel (coal) using the above-mentionedpressurization system including a buffer bin and a pressure lock hopper,it is inevitable that the size of equipment increases, and thusequipment investment cost and operation cost increase.

SUMMARY OF THE INVENTION

Accordingly, the present invention has been devised to solve theabove-mentioned problems, and an object of the present invention is toovercome the conventional problem of utilizing the thermal energy ofsynthesis gas produced by a gasification reaction only to dry afeedstock in a dryer disposed in front of a gasification reactor byrecycling the synthesis gas, thereby providing additional advantages.

In order to accomplish the above object, a first aspect of the presentinvention provides a gasification method of co-producing synthesis gasand high-quality coal, including the steps of: a) supplyingwater-containing coal to a dryer; b) drying the water-containing coal inthe dryer, in which thermal energy necessary for drying thewater-containing coal is supplied in contact with synthesis gas recycledto the dryer from a gasification step; c) separating dried coal andsynthesis gas discharged from the dryer using solid-gas separation andthen recovering the separated synthesis gas; d) recovering a part of theseparated dried coal and simultaneously transferring the residualseparated dried coal to a gasifier in a fluidic state using a loop sealtype transfer means to which aeration gas is supplied by a plurality ofports; e) gasifying the transferred dried coal in the gasifier toprepare synthesis gas; and f) directly recycling the synthesis gas of400 to 1500□ discharged from the gasifier without passing the synthesisgas through a heat exchanger, wherein the dryer provides a dryingcapacity necessary for producing the dried coal separated and recoveredfrom the water-containing coal and the dried coal transferred to thegasification step.

The gasification method may further include the step of separating andrecovering tar generated in the step of drying the water-containing coaland included in the synthesis gas in the step c) of recovering thesynthesis gas.

A second aspect of the present invention provides an integrated dryingand gasification system, including: a gasifier; a dryer disposed infront of the gasifier to dry water-containing coal in contact withsynthesis gas recycled from the gasifier and then discharge dried coaland synthesis gas; a solid-gas separator for separating the dried coaland synthesis gas discharged from the dryer; a recovery unit forseparating and recovering a part of the dried coal separated by thesolid-gas separator; and a loop seal type transfer unit transferring theresidual dried coal not recovered by the recovery unit to the gasifierand including a plurality of aeration gas inlets, wherein the synthesisgas discharged from the gasifier is directly recycled to the dryerwithout passing through a heat exchanger, and the dryer provides adrying capacity necessary for producing the dried coal separated andrecovered from the water-containing coal and the dried coal transferredto the gasification step.

According to an embodiment of the present invention, the separated andrecovered dried coal may be formed into pellets, briquettes or granules.

Further, in the gasification method according to an embodiment of thepresent invention, a drying capacity of water-containing coal (watercontent: 20 to 50 wt %) can be increased by 3 to 4 times compared towhen synthesis gas of 700 to 1500□ discharged from a gasifier is cooledto 301 to 500□ by a heat exchanger disposed behind the gasifier and isthen recycled to a dryer.

BRIEF DESCRIPTION OF THE DRAWINGS

The above and other objects, features and advantages of the presentinvention will be more clearly understood from the following detaileddescription taken in conjunction with the accompanying drawings, inwhich:

FIG. 1 is a simulation graph showing the coal treatment capacitydepending on the content of water in coal when synthesis gas havingpassed through a gasifier and a heat exchanger and synthesis gas havingnot passed therethrough are respectively used as a heat source fordrying water-containing coal;

FIG. 2 is a schematic view showing an integrated drying and gasificationprocess for co-producing synthesis gas, tar and high-quality coal usinga loop seal type transfer means according to an embodiment of thepresent invention; and

FIG. 3 is an enlarged view showing the moving route of dried coal in theloop seal type transfer means of FIG. 2.

REFERENCE NUMERALS

-   -   100: dryer    -   103: cyclone    -   104: downcomer    -   106: drain hopper    -   107: loop seal type transfer means    -   200: pressurized dried coal supply system    -   300: gasifier

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Hereinafter, preferred embodiments of the present invention will bedescribed in detail with reference to the attached drawings.

The above and further objects and novel features of the invention willbe better understood from the following detailed description when thesame is read in connection with the accompanying drawing. It is to beexpressly understood, however, that the drawing is for purpose ofillustration only and is not intended as a definition of the limits ofthe invention.

Coal

According to an embodiment of the present invention, “coal” includesanthracite coal, soft coal (bituminous coal), low-grade coal(Sub-bituminous, brown coal, peat etc.), and the like. Therefore, coalis not limited to specific grade coal, and, particularly, low-grade coalis utilized to the highest degree to increase economical efficiency. Thecontent of carbon in coal by weight may be 20 wt % or more, specifically30 to 80 wt %, and more specifically 40 to 70 wt %, based on the totalweight. Further, the content of ash in dry coal by weight may be 20 wt %or less, specifically 5 to 15 wt %, and more specifically 8 to 12 wt %.The ash includes silica, calcium oxide and iron oxide in large amounts,and includes potassium oxide, magnesium oxide, Mania, zinc oxide and thelike in small amounts.

However, although embodiments of the present invention are describedbased on coal, variously-derived solid fuels, for example,water-containing biomass, water-containing waste and the like, can beused instead of coal as long as they are suitable for an integrateddrying and gasification process and can be obtained in the form ofhigh-quality solid fuel. Therefore, it can be understood that the usageof such various solid fuels is also included in the embodiment of thepresent invention.

According to an embodiment of the present invention, the above-mentionedadvantage can be realized by using water-containing coal as a feedstock,so it is preferred that low-grade coal containing an equivalent amountof water is used. In this case, the content of water in coal may be 10to 70 wt % or less, specifically 20 to 50 wt %, and more specifically 20to 40 wt %. In the case where water-containing coal exists in the formof slurry, the content of solid in stuffy may be 30 to 80 wt %.

Further, in order to allow coal to be easily brought into contact withsynthesis gas and easily transferred in a dryer in the drying step (toallow coal to be easily transferred in the dryer even when synthesis gasis present at comparatively low pressure), the coal may be pulverized toa particle size of 50 to 6000 μm, specifically 50 to 2000 μm, and morespecifically 100 to 1000 μm, and is then introduced into the dryer.

Dryer

According to an embodiment of the present invention, a dryer (dryingregion) is disposed in front of a gasifier. In relation to this,examples of the dryer may include a pneumatic or flash dryer, afluidized-bed dryer, a rotary dryer, a rotary tube dryer and the like.However, in order to effectively remove water, it is advantageous that apneumatic or flash dryer, which can rapidly remove coal because water iseasily diffused, is used as the dryer.

In this embodiment, it is preferred that water-containing coal isclosely brought into contact with synthesis gas recycled from thegasifier (that is, heat-exchanged with synthesis gas) to be heated anddried to generate steam. In this case, as coal is dried, the temperatureof synthesis gas is lowered.

According to an embodiment of the present invention, water-containingcoal is supplied to the lower portion of a dryer, and synthesis gasrecycled from a gasifier is also supplied to the lower portion thereof.In this case, water-containing coal and synthesis gas come into contactwith each other, move toward the top of the dryer in parallel, and aredischarged from the dryer. Selectively, the dryer may be configured suchthat water-containing coal and synthesis gas are introduced into theupper portion of the dryer, come into contact with each other, and movetoward the bottom of the dryer. In this case, considering the dischargeroute (line) of synthesis gas discharged from the gasifier, it isadvantageous that inlets (ports) of water-containing coal and synthesisgas in the dryer are set such that the recycle line thereof issimplified or minimized.

Meanwhile, the operating pressure in the dryer may be adjusted dependingon the operating pressure in the gasifier from which recycled synthesisis discharged. For example, the operating pressure in the dryer may beadjusted in the range of 60 kg/cm² or less.

The operating temperature in the dryer may also be changed depending onthe discharge temperature of synthesis gas recycled from the gasifier.For example, the operating temperature at the inlet of the dryer may beadjusted in the range of 400 to 1500□ and preferably 800 to 1200□, andthe operating temperature at the outlet of the dryer may be adjusted inthe range of 200 to 700□ and preferably 250 to 500□. The dried coal mayhave a water content of 10 wt % or less, specifically 1 to 8 wt %, andmore specifically 1 to 5 wt %.

According to an embodiment of the present invention, it is preferredthat water-containing coal is dried by vaporizing only the water in thewater-containing coal in the dryer. In this case, the degree of dryingof the water-containing coal may be set differently depending on thesupply of the water-containing coal and the temperature and residencetime of synthesis gas in the dryer.

However, according to an embodiment of the present invention, whensynthesis gas is recycled into the dryer in an amount of heat value morethan that of heat value necessary for drying the water-containing coal,volatile components as well as water are separated from thewater-containing coal. Here, such volatile components are included inthe synthesis gas discharged from the dryer in the form of tar.Therefore, in this embodiment, selectively, tar may be separated andrecovered from the synthesis gas, and may be formed into products.

Generally, a dryer, and particularly a flash dryer, is characterized inthat only water is removed from coal in a short residence time whilevolatile components remain in the coal. Therefore, when high-temperaturesynthesis gas stays in the dryer for a long time, volatile components inthe coal is also discharged from the dryer together with synthesis gas,so characteristics, such as heat value and the like, of dried coal arechanged, and subsequent processes are influenced by volatile componentsincluded in synthesis gas, and thus, if possible, it is advantageousthat residence time is set such that only water is removed withoutremoving volatile components. In relation to this, the residence time inthe dryer may be 2 to 10 seconds, specifically 2 to 5 seconds, andspecifically 2 to 3 seconds.

Selectively, it is preferred that, as described above, tar is producedduring the drying process, and the tar is formed into products. In thiscase, when synthesis gas recycled into the dryer is supplied in anamount of heat value more than that of heat value necessary for dryingwater-containing coal or the residence time of synthesis gas in thedryer is maintained relatively long, synthesis gas discharged from thedryer contains tar, and the tar can be separated and recovered from thesynthesis gas.

In this embodiment, as described later, since synthesis gas dischargedfrom the gasifier is directly transferred to the dryer through a pipeline without passing through a heat exchanger, high-temperaturesynthesis gas is introduced, which differs compared to a conventionalintegrated drying and gasification process, and thus the drying capacityof coal also increases.

According to an embodiment of the present invention, a drying capacityof water-containing coal (water content: 20 to 50 wt %) can be increasedby 3 to 4 times compared to when synthesis gas of 400 to 1500□discharged from the gasifier is cooled to 300 to 500□ by the heatexchanger disposed behind the gasifier and is then recycled to thedryer.

The above process conditions in the dryer can be illustrativelyunderstood, and may be changed depending on the size, type and the likeof the dryer.

FIG. 1 is a graph showing the simulation test results (SK pilot plant:capacity of 3 ton/day) of the coal treatment capacity depending on thecontent of water in coal when synthesis gas (350□) having passed througha gasifier and a heat exchanger and synthesis gas (700□) having notpassed through the heat exchanger are respectively used as a heat sourcefor drying water-containing coal in the dryer (integrated dryer)according to an embodiment of the present invention.

The test conditions and the change in coal treatment capacity dependingon water content are shown in Tables 1 and 2 below.

TABLE 1 Content of water in coal after drying (%) 2 Temperature atoutlet of dryer Min. 200□

TABLE 2 Coal treatment rate depending on synthesis gas Content of watertemperature (kg/hr) in coal (%) 350□ 700□ 20 171 582 25 144 491 30 124424 35 109 374 40 98 334 45 88 302 50 81 275

Loop Seal Type (Non-Mechanical Valve Type) Pressurized Dried Coal SupplySystem

According to an embodiment of the present invention, dried coal andsynthesis gas (specifically, steam-containing synthesis, which generallycontains steam in an amount of 10 to 50 mol %) discharged from a dryeris transferred to a dried coal supply system including a solid-gasseparator, a recovery unit for additionally separating and recovering apart of separated dried coal and a loop seal type transfer means fortransferring residual dried coal to a gasifier. Specifically, productsdischarged from the dryer are separated into dried coal and synthesisgas by the solid-gas separator. Here, as the solid-gas separator, acommonly-known solid-gas separator may be used. A cyclone separator isan example of a typical solid-gas separator.

The cyclone is an apparatus for separating particles existing in fluid(gas) using centrifugal force, and includes a tangential inlet forintroducing solid-containing gas, an outlet for dischargingsolid-containing gas and an outlet for discharging collected solids.According to an embodiment of the present invention, the cycloneincludes a cylindrical portion and a conic portion connected to thecylindrical portion, and is configured such that the upper end of adowncomer is connected with the narrow lower end of the conic portion ofthe cyclone. The inlet of the downcomer is connected with the soliddischarging outlet of the cyclone, and may have a pipe shape. The lowerportion of the downcomer constitutes a part of the following loop sealtype transfer means.

A part of the separated dried coal is additionally separated and thenrecovered by the recovery unit before it is transferred to a gasifier.Here, the recovery unit may be a drain hopper, a continuousdepressurization drain unit or the like.

As described above, dried coal is obtained by removing a large amount ofwater from a feedstock, and may become high-quality coal existing in theform of particle when it is selectively pulverized before it is dried.Therefore, the dried coal has properties suitable for formation orfabrication into pellets, briquettes or granules. As such, the driedcoal is advantageous in that it is a high value-added coal, and that,when it is formed or fabricated into a product, treatability andtransportability as well as added value can be improved.

According to an embodiment of the present invention, the recovered driedcoal may be formed into pellets using an organic or inorganic binderknown in the related field. The organic binder may be acrylic emulsion,acryl-styrene emulsion, cellulose ether, polyvinyl alcohol, phenolresin, polyimide or a mixture thereof. The inorganic binder may bebentonite or the like. Specifically, dried coal is mixed with thebinder, and then the mixture is kneaded, pelletized by a forming machineand then dried and cooled to be formed into a product. If necessary,dried coal may be palletized without using the binder. For example, apart of dried coal is heated to the softening point thereof, and is thenpressurized to allow it to be agglomerated into naturally-present tarand pitch. The above-mentioned process of forming dried coal into aproduct can be illustratively understood. Therefore, another process offorming dried coal into a product, known in the related field, may beadopted as long as it can suitably utilize high-quality dried coal.

Meanwhile, non-recovered dried coal is transferred to a gasifier as afeedstock for a gasification reaction. As will be described later, thegasifier is operated at a pressure of several to several tens of kg/cm².Therefore, the pressure of synthesis gas discharged from the gasifier ispartially lowered during a process of transferring it to the dryer and aprocess of drying it in the dryer, and the pressure of the fuel supplyunit and reaction unit of the gasifier is high compared to the pressureof the discharge unit of the gasifier, so the pressure of the dried coalis lower than the pressure in the gasifier. Therefore, in order totransfer (supply) the dried coal into the gasifier, that is, in orderfor solids to move from a low-pressure region to a high-pressure region,the dried coal must be supplied at pressure higher than the pressure inthe gasifier.

For this purpose, in this embodiment, dried coal is transferred to thegasifier by forming a static head of the fluidized dried coal using aloop seal type transfer means. In this case, high-pressure (higher thanpressure in loop seal structure) aeration gas is supplied through aplurality of ports provided in the loop seal structure. In the loop sealstructure, the supplied high-pressure aeration gas forms the coalinventory in the loop seal structure into a fluidized layer andmaintains the fluidized layer, thus enabling the dried coal to betransferred to the gasifier.

In this case, as the aeration gas, nitrogen, carbon dioxide, steam,synthesis gas generated from the gasifier or a mixture thereof may beused.

Gasifier

According to an embodiment of the present invention, as a gasifier,various types of reactors known in the related field may be used. Thegasifier is provided with a dried coal inlet and, if necessary, agasifying agent inlet. Examples of a gasifier may include a moving-bedgasifier (dried carbonaceous feedstock is introduced into the upperportion thereof, and a gasifying agent comes into contact with the feedstock in a counterflow manner in the lower portion thereof), afluidized-bed gasifier (a gasifying agent floats solid particles whilepassing through a carbonaceous feedstock bed), a transportreactor-integrated gasifier, a distributary flow gasifier (acarbonaceous feedstock and a gasifying agent are introduced inparallel), and the like.

According to an embodiment of the present invention, the operatingtemperature in the gasifier may be 400 to 1500□, specifically 800 to1500□, and more specifically 900 to 1500□. Further, the operatingpressure in the gasifier may be 1 to 60 kg/cm², specifically 5 to 40kg/cm², and more specifically 20 to 40 kg/cm². Further, the molar ratioof O₂/C may be 0.1 to 1.0, and specifically 0.2 to 0.7.

However, in this embodiment, the molar ratio of steam/C may besubstantially adjusted to 0 (in the case of a dry gasification reactionor a gasification reaction by reforming carbon dioxide. In this case,the molar ratio of steam/C may be 0 to 2, and specifically 0 to 1.Further, the molar ratio of CO₂/C may be 0 to 1, and specifically 0 to0.5.

According to an embodiment of the present invention, in the gasificationreaction, the conversion ratio of carbon in coal may be 80% or more, andspecifically 90 to 99%.

Meanwhile, according to an embodiment of the present invention, sincethe produced synthesis gas is discharged from the gasifier at hightemperature depending on the operating temperature in the gasifier, thissynthesis gas is directly recycled into the dryer without passingthrough a heat exchanger.

FIG. 2 schematically shows an integrated drying and gasification processfor co-producing synthesis gas, tar and high-quality coal using a loopseal type transfer means according to an embodiment of the presentinvention.

In FIG. 2, the integrated drying gasification process largely includes adryer 100, a pressurized dried coal supply system 200 and a gasifier300. If not particularly mentioned, the constituents in the integrateddrying gasification process may be connected with each other by acommonly-used connecting means, for example, a pipe, and coal and gasmay be transferred there between through the connecting means.

In this embodiment, water-containing coal is introduced into the lowerportion of the dryer 100, and synthesis gas directly recycled from thegasifier 300 is also introduced into the lower portion of the dryer 100.In this case, as described above, the temperature of the synthesis gasdischarged from the gasifier 300 is not greatly different from theoperating temperature of the gasifier 300, but the synthesis gas may becooled to 20˜100□ during the process of recycling this synthesis gasinto the dryer 100. However, as shown in FIG. 2, since the synthesis gasis not arbitrarily cooled by a heat exchanger, the dryer is designed tohave a drying capacity higher than that of a dryer used in a generalintegrated drying and gasification process.

Further, in this embodiment, dried coal and a gas mixture are dischargedfrom the upper portion of the dryer 100, and the content of water ineach of the discharged dried coal and gas mixture is determineddepending on the temperature and pressure of synthesis gas introducedinto the dryer 100, the initial water content and particle size of awater-containing coal feedstock and the mixing ratio of synthesis gasand coal (feedstock) introduced into the dryer 100. Here, the weightratio of synthesis gas and water-containing coal introduced into thedryer 100 may be 1:1 to 10:1, specifically 2:1 to 8:1, and morespecifically 3:1 to 6:1.

Further, in this embodiment, dried coal (that is, dried solid fuel) andsynthesis gas are transferred from the top of the dryer 100 to thepressurized dried coal supply system 200 through a line 101. The driedcoal supply system 200 largely includes a cyclone 103, which is asolid-gas separator, a drain hopper 106 and a loop seal type transfermeans 107. The cyclone 103 serves to separate a gaseous component(synthesis gas) and a solid component (dried coal). In this case, sincethe separated synthesis gas 102 may include dust, sulfur compounds,nitrogen compounds and the like, it may be additionally pass through apost-treatment process (not shown) provided with a filter (ceramicfilter), an electric dust collector, a scrubber, a desulfurizer and thelike. For example, the synthesis gas 102 separated in this way may besupplied to a subsequent process such as an integrated gasificationcombined cycle (IGCC) process, an F-T process or the like. Further, asdescribed above, when tar is included in the synthesis gas, a means orprocess for separating and recovering tar (not shown) may beadditionally provided. As the means for separating and recovering tar, ameans commonly used in the related field (for example, filter or thelike) may be used.

Meanwhile, dried coal separated by the cyclone 103 moves downwards alonga downcomer 104 connected with the lower end of the cyclone 103(accurately, the lower end of a conic portion of the cyclone 103). Inthis case, the downcomer 104 is provided at the lower portion thereofwith a dried coal separation line 105, and the dried coal separationline 105 is connected with a drain hopper 106, thus recovering driedcoal.

Meanwhile, residual dried coal, which is not separated and recovered, isintroduced into a loop seal type transfer means 107. According to anembodiment of the present invention, the content ratio of separated andrecovered dried coal to dried coal transferred to the gasifier may besuitably changed depending on the amount of a desired target product(synthesis gas or high-quality dried coal). For example, the contentratio thereof by weight may be 1:1 to 4:1, and specifically 2:1 to 3:1.

FIG. 3 shows the moving route of dried coal in the loop seal typetransfer means in the integrated drying gasification process shown inFIG. 2.

As shown in FIG. 3, the loop seal type transfer means 107 is providedwith a plurality of aeration gas injecting ports. In this case, driedcoal sequentially passes through the lower end of the downcomer 104, thehorizontal region of the loop seal type transfer means 107 and thevertical region of the loop seal type transfer means 107 to betransferred toward the high-pressure gasifier 300.

Meanwhile, in the gasifier 300, the transferred dried coal is gasifiedby various reaction routes (partial oxidation, carbon dioxide reforming,steam reforming, and combinations thereof) in the presence of agasifying agent to produce synthesis gas. In this case, when aerationgas supplied from the loop seal type transfer means is used as agasifying agent, since the aeration gas is also introduced into thegasifier 300, the amount of the gasifying agent introduced into agasifying agent injection port (inlet) provided in the gasifier may beadjusted.

After the gasification reaction is completed, the synthesis gas producedby the gasification reaction is partially or entirely recycled into thedryer 100 through a line 108. According to an embodiment of the presentinvention, when the synthesis gas is entirely recycled into the dryer100, the conversion rate of water-containing coal into dried coal can bemaximized. In this case, the molar ratio of carbon monoxide in thedischarged synthesis gas may be 10 to 50%, and specifically 20 to 40%.

As described above, according to the integrated drying and gasificationprocess of the present invention, coal dried by synthesis gas issupplied to a gasifier by a non-mechanical valve-type transfer meanssuch as a loop seal type transfer means, so process equipment can besimplified and can be easily operated. Further, according to thegasification process of the present invention, the dryability ofwater-containing coal can be increased compared to a conventionaltechnology in which synthesis gas is cooled by a heat exchanger disposedbehind a gasifier and is then recycled to a dryer, and a part of driedcoal is recovered as high-quality coal and is then formed into pellets,briquettes, granules and the like. Furthermore, according to thegasification process of the present invention, tar, which is caused byvolatile components separated from coal according to the degree of theselective supply of heat to synthesis gas in the step of drying thewater-containing coal, can be separated and recovered from the synthesisgas and can be formed into products.

As such, according to the gasification process of the present invention,when a feedstock for a gasification reaction and high-quality coal canbe simultaneously produced from low-quality water-containing coal, aloop seal type transfer means is used instead of a conventional lockhopper, so a process can be simplified and the problem of investmentcost being increased by the increase in size of the transfer means canbe overcome. Moreover, according to the gasification process of thepresent invention, a heat exchanger, which is generally used in aconventional integrated drying and gasification process, is not needed,so equipment investment cost can be reduced. Further, if necessary, taris additionally separated from synthesis gas and formed into products,thus increasing added value.

Although the preferred embodiments of the present invention have beendisclosed for illustrative purposes, those skilled in the art willappreciate that various modifications, additions and substitutions arepossible, without departing from the scope and spirit of the inventionas disclosed in the accompanying claims.

What is claimed is:
 1. A gasification method of co-producing synthesisgas and high-quality coal, comprising the steps of: a) supplyingwater-containing coal to a dryer; b) drying the water-containing coal inthe dryer, in which thermal energy necessary for drying thewater-containing coal is supplied in contact with synthesis gas recycledto the dryer from a gasification step; c) separating dried coal andsynthesis gas discharged from the dryer using solid-gas separation andthen recovering the separated synthesis gas; d) recovering a part of theseparated dried coal and simultaneously transferring the residualseparated dried coal to a gasifier in a fluidic state using a loop sealtype transfer means to which aeration gas is supplied by a plurality ofports; e) gasifying the transferred dried coal in the gasifier toprepare synthesis gas; and f) directly recycling the synthesis gas of400 to 1500□ discharged from the gasifier without passing the synthesisgas through a heat exchanger(s), wherein the dryer provides a dryingcapacity necessary for producing the dried coal separated and recoveredfrom the water-containing coal and the dried coal transferred to thegasification step.
 2. The gasification method of claim 1, wherein thecontent of water in the water-containing coal is 10 to 70 wt %.
 3. Thegasification method of claim 1, wherein the dried coal has a watercontent of 10 wt % or less.
 4. The gasification method of claim 1,wherein the water-containing coal is pulverized to a particle size of 50to 6000 μm and then introduced into the dryer, before the step a). 5.The gasification method of claim 1, wherein the content of carbon in thewater-containing coal is at least 20 wt %.
 6. The gasification method ofclaim 1, wherein the dryer is a pneumatic or flash dryer, afluidized-bed dryer, a rotary dryer or a rotary tube dryer.
 7. Thegasification method of claim 6, wherein the dryer is a pneumatic orflash dryer.
 8. The gasification method of claim 1, wherein thewater-containing coal and synthesis gas are in contact with each otherin a parallel stream in the dryer.
 9. The gasification method of claim1, wherein the operating pressure in the dryer is 60 kg/cm² or less, theoperating temperature at an inlet of the dryer is adjusted in a range of400 to 1500□, and the operating temperature at an outlet of the dryer isadjusted in a range of 200 to 700□.
 10. The gasification method of claim1, further comprising the step of forming the dried coal separated andrecovered in the step d) into pellets, briquettes or granules.
 11. Thegasification method of claim 1, the aeration gas is nitrogen, carbondioxide, steam, synthesis gas generated from the gasifier, or a mixturethereof.
 12. The gasification method of claim 1, wherein the operatingtemperature in the gasifier is 400 to 1500□, and the operating pressurein the gasifier is 1 to 60 kg/cm².
 13. The gasification method of claim1, wherein, in the step e), the molar ratio of O₂/C is 0.1 to 1.0, andthe molar ratio of CO₂/C is 0 to
 1. 14. The gasification method of claim1, wherein, in the step e), the molar ratio of steam/C is 0 to
 2. 15.The gasification method of claim 1, wherein the weight ratio ofsynthesis gas recycled to the dryer in the step b): water-containingcoal is 1:1 to 10:1.
 16. The gasification method of claim 1, wherein theweight ratio of dried coal separated and recovered in the step d): driedcoal transferred to the gasifier is 1:1 to 4:1.
 17. The gasificationmethod of claim 1, further comprising the step of separating andrecovering tar generated in the step of drying the water-containing coaland included in the synthesis gas in the step c) of recovering thesynthesis gas.
 18. The gasification method of claim 17, wherein thedryer provides a heat capacity larger than a drying capacity necessaryfor producing the dried coal separated and recovered from thewater-containing coal and the dried coal transferred to the gasificationstep.
 19. An integrated drying and gasification system, comprising: agasifier; a dryer disposed in front of the gasifier to drywater-containing coal in contact with synthesis gas recycled from thegasifier and then discharge dried coal and synthesis gas; a solid-gasseparator for separating the dried coal and synthesis gas dischargedfrom the dryer; a recovery unit for separating and recovering a part ofthe dried coal separated by the solid-gas separator; and a loop sealtype transfer unit transferring the residual dried coal not recovered bythe recovery unit to the gasifier and including a plurality of aerationgas inlets, wherein the synthesis gas discharged from the gasifier isdirectly recycled to the dryer without passing through a heat exchanger,and the dryer provides a drying capacity necessary for producing thedried coal separated and recovered from the water-containing coal andthe dried coal transferred to the gasification step.
 20. The integrateddrying and gasification system of claim 19, further comprising arecovery unit for separating and recovering tar included in thesynthesis gas separated by the solid-gas separator.
 21. The integrateddrying and gasification system of claim 19, wherein the recovery unitfor recovering the dried coal is a drain hopper or a continuousdepressurization drain unit.